The use of Raman spectroscopy in the characterization of variscite provenance: The Gavà case

Joan Carlos Melgarejo, Laia Arqués, Cristina Villanova-de-Benavent, Tariq Jahwari, Lisard Torró, Josep Bosch Argilagós, Montgarri Castillo-Oliver, Marc Campeny, Sandra Amores, Aleu Andreazini, Saleh Lehbib, Antoni Camprubí

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Resumen

The Gavà phosphate deposit, mined during the Neolithic, was produced by weathering processes affecting primary apatite beds. It exhibits a neat vertical zoning, related to chemical gradients during weathering. Strengite, yellowish Al-rich strengite and ferroan variscite are found at the top, palegreen variscite at the intermediate levels, and green variscite in depth. Fe values are very low in the greenish samples, as well as Cr and V. Raman spectrums of the Gavà variscite show differences with samples from other occurrences worldwide. Moreover, some spectral differences can also be observed in the Raman spectra of variscite coming from different depths in the deposit. Raman spectroscopy can be an efficient tool to discriminate not only samples from different geographical localities, but also from its original position in a given deposit.

Idioma originalInglés
Título de la publicación alojadaLa parure en callaïs du Néolithique européen
EditorialArchaeopress
Páginas241-251
Número de páginas11
ISBN (versión impresa)9781789692808
EstadoPublicada - 29 ago. 2019
Publicado de forma externa

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