Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

Joaquín Cortés; Gloria Troncoso; Luis Alzamora; Eliana Valencia

doi:10.1039/F19858101631

Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

Joaquín Cortés, Gloria Troncoso, Luis Alzamora, Eliana Valencia

Facultad de Ciencias Físicas y Matemáticas de la Universidad de Chile

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

4 Citas (Scopus)

Resumen

A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.

Idioma original	Inglés
Páginas (desde-hasta)	1631-1636
Número de páginas	6
Publicación	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volumen	81
N.º	7
DOI	https://doi.org/10.1039/F19858101631
Estado	Publicada - 1985
Publicado de forma externa	Sí

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@article{2853c6febda74fc5b8e0d86035c7ec0c,

title = "Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil",

abstract = "A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.",

author = "Joaqu{\'i}n Cort{\'e}s and Gloria Troncoso and Luis Alzamora and Eliana Valencia",

year = "1985",

doi = "10.1039/F19858101631",

language = "English",

volume = "81",

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journal = "Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases",

issn = "0300-9599",

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TY - JOUR

T1 - Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

AU - Cortés, Joaquín

AU - Troncoso, Gloria

AU - Alzamora, Luis

AU - Valencia, Eliana

PY - 1985

Y1 - 1985

N2 - A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.

AB - A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.

UR - https://www.scopus.com/pages/publications/37049109994

U2 - 10.1039/F19858101631

DO - 10.1039/F19858101631

M3 - Article

AN - SCOPUS:37049109994

SN - 0300-9599

VL - 81

SP - 1631

EP - 1636

JO - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

JF - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

IS - 7

ER -

Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

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