Robust antiferromagnetism and structural disorder in Bi xCa 1-xFeO 3 perovskites

Wei Tin Chen, Anthony J. Williams, Luis Ortega-San-Martin, Ming Li, Derek C. Sinclair, Wuzong Zhou, J. Paul Attfield

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53 Citas (Scopus)

Resumen

An investigation of Ca substitution in the multiferroic material BiFeO 3 shows that a wide range of perovskites Bi xCa 1-xFeO 3 (0.4 ≤ × ≤ 1.0) can be prepared by sintering in air at 810-960 °C. 0.4 ≤ × ≤ 0.8 samples are cubic Pm3̄m, whereas x = 0.8 and 0.9 show a coexistence of the cubic and the rhombohedral R3c BiFeO 3-type structure. Considerable disorder arising from Bi 3+ lone-pair distortions is evidenced by synchrotron X-ray and neutron studies of the average structures of the cubic phases, and electron microscopy reveals commensurate and incommensurate local superstructures. The Bi xCa 1-xFeO 3 (0.4 ≤ × ≤ 1.0) materials show a remarkably robust antiferromagnetic order with T N = 623-643 K and ordered moments of 3.6-4.1 μ B. They are "leaky" dielectrics with relative permittivities of ∼30-100 and bulk resistivities ∼50-500 kω cm at room temperature. The activation energy for bulk conduction increases from 0.27 eV for x = 0.4 to 0.5 eV for x = 1, but with a discontinuity at the cubic-rhombohedral boundary. Further processing of the x = 0.8 and 0.9 compositions to reduce conductivity through control of oxygen content could lead to improved BiFeO 3-based multiferroics.

Idioma originalInglés
Páginas (desde-hasta)2085-2093
Número de páginas9
PublicaciónChemistry of Materials
Volumen21
N.º10
DOI
EstadoPublicada - 26 may. 2009
Publicado de forma externa

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