Publicación
Photo-induced electron transfer dynamics and its mid-IR modulation of an ethyne bridged donor-acceptor complex
Resumen
Electron transfer (ET) rate in donor–bridge–acceptor (DBA) complexes is modulated by the alkyne bridge vibrational excitation. Torsion angle ( θ ) offers selectivity in accessing locally-excited, acceptor-centered (S 2 ) state of the DBA complex.
Autores y colaboradores
Authors
Kasun C. Mendis
Li Xiao
S. D. Cox
Peng Zhang
Nisansala S S Thalaththani Rallage
Tong Ren
David N. Beratan
Igor V. Rubtsov
Palabras clave
EXCITED-STATE DYNAMICS INTRAMOLECULAR CHARGE-TRANSFER 1ST HYPERPOLARIZABILITY VIBRATIONAL CONTROL MOLECULES DEPENDENCE FERROCENE BOND ABSORPTION SEPARATION