Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

Joaquín Cortés; Gloria Troncoso; Luis Alzamora; Eliana Valencia

doi:10.1039/F19858101631

Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

Joaquín Cortés, Gloria Troncoso, Luis Alzamora, Eliana Valencia

Facultad de Ciencias Físicas y Matemáticas de la Universidad de Chile

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.

Original language	English
Pages (from-to)	1631-1636
Number of pages	6
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	81
Issue number	7
DOIs	https://doi.org/10.1039/F19858101631
State	Published - 1985
Externally published	Yes

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10.1039/F19858101631

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title = "Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil",

abstract = "A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.",

author = "Joaqu{\'i}n Cort{\'e}s and Gloria Troncoso and Luis Alzamora and Eliana Valencia",

year = "1985",

doi = "10.1039/F19858101631",

language = "English",

volume = "81",

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T1 - Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

AU - Cortés, Joaquín

AU - Troncoso, Gloria

AU - Alzamora, Luis

AU - Valencia, Eliana

PY - 1985

Y1 - 1985

N2 - A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.

AB - A study has been made of the different contributions to the entropy of adsorption in Henry's zone of several hydrocarbons on Aerosil with different degrees of hydrophobicity. The statistical-mechanical interpretation of the experiments on the adsorption of isobutene on hydroxylated Aerosil shows that there is mobile adsorption with loss of one rotational degree of freedom.

UR - http://www.scopus.com/inward/record.url?scp=37049109994&partnerID=8YFLogxK

U2 - 10.1039/F19858101631

DO - 10.1039/F19858101631

M3 - Article

AN - SCOPUS:37049109994

SN - 0300-9599

VL - 81

SP - 1631

EP - 1636

JO - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

JF - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

IS - 7

ER -

Rotational degrees of freedom in the adsorption of hydrocarbons on aerosil

Abstract

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