Abstract
A study of the adsorption of n-butane, buta-1,3-diene and isobutene on Aerosil treated at different temperatures has been made from 17.7 to 45 °C and over the pressure range 0-600 Torr. The isosteric enthalpy and entropies of adsorption at zero coverage together with the B.E.T. parameters C and nm of the systems have been examined; they suggest a way in which different parts of the adsorbate molecule are specifically related to the hydroxylated and non-hydroxylated regions of the Aerosil surface.
| Original language | English |
|---|---|
| Pages (from-to) | 2127-2132 |
| Number of pages | 6 |
| Journal | Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases |
| Volume | 80 |
| Issue number | 8 |
| DOIs | |
| State | Published - 1984 |
| Externally published | Yes |
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