A Selective Electrochemical Sensor for the Detection of Cd(II) Based on a Carbon Paste Electrode Impregnated with a Novel Ion-imprinted Hybrid Polymer

Anais Adauto; Ademar Wong; Sabir Khan; Gino Picasso; María del Pilar Taboada Sotomayor

doi:10.1002/elan.202100007

A Selective Electrochemical Sensor for the Detection of Cd(II) Based on a Carbon Paste Electrode Impregnated with a Novel Ion-imprinted Hybrid Polymer

Anais Adauto
, Ademar Wong
, Sabir Khan
, Gino Picasso
, María del Pilar Taboada Sotomayor

Universidad Nacional de Ingenieriá
Sao Paulo State University
National Institute for Alternative Technologies of Detection

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

An electrochemical sensor (CPE-IIHP) was developed for Cd(II) using a carbon paste electrode (CPE) impregnated with an ion-imprinted hybrid polymer (IIHP). A CPE-NIHP was also prepared for comparison. DPASV was used to optimize the sensor response and quantify Cd(II). The sensor presented a wide linear range from low concentrations of Cd(II): 1 to 100 μg L⁻¹ and high concentrations of Cd(II): 2.75 to 5.0 mg L⁻¹. Ions such as Co(II), Pb(II), Ni(II), Zn(II), Fe(II), Fe(III), Sn(II) and Cu(II), showed no variation in the Cd(II) signal. The CPE-IIHP was successfully applied in river and drinking water analysis, revealing the great potential for its application.

Original language	English
Pages (from-to)	1557-1566
Number of pages	10
Journal	Electroanalysis
Volume	33
Issue number	6
DOIs	https://doi.org/10.1002/elan.202100007
State	Published - Jun 2021
Externally published	Yes

Keywords

Cd(II)
Ion-imprinted polymer
carbon paste electrode
electrochemical sensors

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10.1002/elan.202100007

Cite this

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title = "A Selective Electrochemical Sensor for the Detection of Cd(II) Based on a Carbon Paste Electrode Impregnated with a Novel Ion-imprinted Hybrid Polymer",

abstract = "An electrochemical sensor (CPE-IIHP) was developed for Cd(II) using a carbon paste electrode (CPE) impregnated with an ion-imprinted hybrid polymer (IIHP). A CPE-NIHP was also prepared for comparison. DPASV was used to optimize the sensor response and quantify Cd(II). The sensor presented a wide linear range from low concentrations of Cd(II): 1 to 100 μg L−1 and high concentrations of Cd(II): 2.75 to 5.0 mg L−1. Ions such as Co(II), Pb(II), Ni(II), Zn(II), Fe(II), Fe(III), Sn(II) and Cu(II), showed no variation in the Cd(II) signal. The CPE-IIHP was successfully applied in river and drinking water analysis, revealing the great potential for its application.",

keywords = "Cd(II), Ion-imprinted polymer, carbon paste electrode, electrochemical sensors",

author = "Anais Adauto and Ademar Wong and Sabir Khan and Gino Picasso and \{del Pilar Taboada Sotomayor\}, Mar{\'i}a",

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doi = "10.1002/elan.202100007",

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AU - Adauto, Anais

AU - Wong, Ademar

AU - Khan, Sabir

AU - Picasso, Gino

AU - del Pilar Taboada Sotomayor, María

PY - 2021/6

Y1 - 2021/6

N2 - An electrochemical sensor (CPE-IIHP) was developed for Cd(II) using a carbon paste electrode (CPE) impregnated with an ion-imprinted hybrid polymer (IIHP). A CPE-NIHP was also prepared for comparison. DPASV was used to optimize the sensor response and quantify Cd(II). The sensor presented a wide linear range from low concentrations of Cd(II): 1 to 100 μg L−1 and high concentrations of Cd(II): 2.75 to 5.0 mg L−1. Ions such as Co(II), Pb(II), Ni(II), Zn(II), Fe(II), Fe(III), Sn(II) and Cu(II), showed no variation in the Cd(II) signal. The CPE-IIHP was successfully applied in river and drinking water analysis, revealing the great potential for its application.

AB - An electrochemical sensor (CPE-IIHP) was developed for Cd(II) using a carbon paste electrode (CPE) impregnated with an ion-imprinted hybrid polymer (IIHP). A CPE-NIHP was also prepared for comparison. DPASV was used to optimize the sensor response and quantify Cd(II). The sensor presented a wide linear range from low concentrations of Cd(II): 1 to 100 μg L−1 and high concentrations of Cd(II): 2.75 to 5.0 mg L−1. Ions such as Co(II), Pb(II), Ni(II), Zn(II), Fe(II), Fe(III), Sn(II) and Cu(II), showed no variation in the Cd(II) signal. The CPE-IIHP was successfully applied in river and drinking water analysis, revealing the great potential for its application.

KW - Cd(II)

KW - Ion-imprinted polymer

KW - carbon paste electrode

KW - electrochemical sensors

UR - https://www.scopus.com/pages/publications/85103058471

U2 - 10.1002/elan.202100007

DO - 10.1002/elan.202100007

M3 - Article

AN - SCOPUS:85103058471

SN - 1040-0397

VL - 33

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JO - Electroanalysis

JF - Electroanalysis

IS - 6

ER -

A Selective Electrochemical Sensor for the Detection of Cd(II) Based on a Carbon Paste Electrode Impregnated with a Novel Ion-imprinted Hybrid Polymer

Abstract

Keywords

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